The four people in the room include a man and woman and a boy and girl. If the adults are brother and sister and each of them is parent to one of the children, that would leave all of the roles fulfilled.
There is not enough information to tell which child is the man's and which is the woman's, though, so I cannot tell you the full set of relationships.
[written]
There is not enough information to tell which child is the man's and which is the woman's, though, so I cannot tell you the full set of relationships.